solar cells perovskite - calcium titanate

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solar cells perovskite - calcium titanate




by jean.caissepas » 20/05/14, 14:55

Hello,

researchers seem to have found a new "miracle" material to produce photovoltaic ones, or light emitters ...

A new type of solar cell based on perovskite material - named after scientist Lev Perovski, who discovered this calcium titanate mineral in the Ural Mountains in the 12th century - was recently launched by a team of researchers by Professor Henry Snaith of Oxford University.

Solar cells in perovskite are a source of great excitement in the research community because they are already positioned only a short distance behind conventional silicon, having reached 17% efficiency after only two years of research. They open up the prospect of large-scale, economical solar energy production.


Link : http://www.enerzine.com/1/17107+des-cellules-solaires-revolutionnaires-agissent-comme-des-lasers+.html

Good reading !
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Re: Perovskite solar cells - calcium titanate




by moinsdewatt » 21/03/16, 21:39

it becomes promising:

Perovskite solar cells achieve a yield of 21,1%

21 Mars 2016 enerzine

EPFL scientists have achieved the highest reproducibility ever achieved for perovskite solar cells, combined with a yield that pushes the limits to 21.1% under normal conditions of use.

Solar cells in perovskite are very promising in terms of cost-effective solar energy. However, thermal stability is a problem because it can significantly limit the performance of a solar cell in the long run. A team of scientists led by Michael Grätzel's laboratory at EPFL succeeded in developing a perovskite solar cell containing cesium that reached a yield of 21,1%, as well as a world record of reproductivity. This work is published in Energy and Environmental Science.

By adding cesium, EPFL scientists, led by postdoctoral researcher Michael Saliba, developed the first triple-cation perovskite compound (Cs / MA / FA). The new films are more heat stable and less affected by fluctuating environmental variables, such as temperature, solvent vapors, or the heating protocol used for the device. More importantly, they show stabilized conversion efficiencies of 21,1%, and output rates of 18% under operational conditions, even beyond 250 hours.

"It's an absolute breakthrough," said Michael Saliba. "These properties are decisive for the marketing of perovskite photovoltaics, particularly as reproducibility and stability are the main requirements for profitable, large-scale production of perovskite solar cells."

[Read more]

This study results from a collaboration of the following EPFL laboratories: Laboratory of Photonics and Interfaces, Laboratory of Photomolecular Sciences, Group for Molecular Engineering of Functional Materials and Panasonic Corporation.

The project was funded by the Seventh Framework Program for Research and Technological Development of the European Union, SNSF-NanoTera (SYNERGY) and the Swiss Federal Office of Energy (SYNERGY), CCEM-CH, and King Abdulaziz City for Science and Technology (KACST).

Source

Saliba M, Matsui T, Seo JY, Domanski K, Correa-Baena JP, Nazeeruddin MK, SM Zakeeruddin, Tress W, Abate A, Hagfeldt A, Cesium-containing Grätzel M. Triple Cation Perovskite Solar Cells: Improved Stability, Reproducibility and High Efficiency.Energy and Environmental Science 16 March 2016. DOI: 10.1039 / C5EE03874J


http://www.enerzine.com/1/19155+des-cel ... 1pct+.html
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Re: Perovskite solar cells - calcium titanate




by izentrop » 23/03/16, 11:16

moinsdewatt wrote:they show stabilized conversion efficiencies of 21,1%, and output rates of 18% under operational conditions, even beyond 250 hours.

Hello,
18% this is what some crystalline cells reach http://fr.enfsolar.com/pv/cell
I guess they will be cheaper on the market;)
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Re: Perovskite solar cells - calcium titanate




by moinsdewatt » 08/12/16, 17:08

For the Perovskite the battle is now to get to increase the size of the cells, with yield.

Large perovskite solar cell efficiency 12%

December 05, 2016

The race to boost the efficiency of large solar cells continues at the University of New South Wales in Australia claiming a new record figure of 12% and looking to double the performance within the next year.

Image

The 12.1 16 perovskite solar cell, the largest single perovskite photovoltaic cell with the highest energy conversion efficiency, Newport Corp. in Bozeman, Montana. The new cell is at least 10 times bigger than the current high-efficiency certified perovskite solar cells on record.

The team also achieved an 18% efficiency rating on a 1.2 cm 2 single perovskite cell, and an 11.5% for a 16 2 cm-cell perovskite mini-module with a process that allows larger grains to form.

"This is a very hot area of ​​research, with many teams competing to advance photovoltaic design," said Anita Ho-Baillie, a Senior Research Fellow at the Australian Center for Advanced Photovoltaics (ACAP), and leader of the reaearch team (above). . "Perovskites come out of nowhere in 2009, with an efficiency rating of 3.8%, and have since grown in leaps and bounds. ! think we can get to 24% within a year or so. "The project's goal is to lift perovskite solar cell efficiency to 26%.

Perovskites use a hybrid organic-inorganic lead or tin halide-based material as the light-harvesting active layer and are popular because the compound is cheap to produce and simple to manufacture at low temperatures, and can even be sprayed onto surfaces. “The versatility of solution deposition of perovskite makes it possible to spray-coat, print or paint on solar cells,” said Ho-Baillie. “The diversity of chemical compositions also allows cells be transparent, or made of different colors."

The research is part of a $ 3.6 million (US $ 2.6 m, € 2.5m) project for the Australian Renewable Energy Agency's (ARENA) 'solar excellence' initiative.


http://www.smart2zero.com/news/large-pe ... cy-hits-12
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Re: Perovskite solar cells - calcium titanate




by moinsdewatt » 29/03/17, 19:58

So it's really starting to get damn interesting:

Flexible roll-to-roll perovskite solar cells hit record efficiency

March 10, 2017 // By Nick Flaherty

Image

A pan-European collaboration has achieved a record of efficiency of 12.6% for flexible roll-to-roll solar cells using perovskite materials.

Solliance, a grouping of research centers and companies from Holland, Belgium and Germany with Solartek, Dyesol and Panasonic, has used an industrially-applicable roll-to-roll process for the production of these cells, paving the way to an accelerated market introduction.

Perovskite microcrystals are a promising material to make high-yielding, thin-film solar cells. They may be processed into thin, light-weight and potentially semitransparent modules that could eventually be integrated into building materials. Solliance and its research partners focus on scalable, industrial processes towards the manufacturing of large-area modules, eventually becoming integrated into a wide variety of PV systems.

The current world record efficiency of a small, lab scale perovskite-based PV cell is 22.1%, while other roll to roll technologies using organic dyes have reached 13%.

“The challenge is to upscale perovskite cells to larger size, industrially-manufacturable modules with high efficiency and long lifetime at low cost,” said Ronn Andriessen, Program Director at Solliance. “These 12.6% R2R up-scaled perovskite-based solar cells are a first and important step in this development. With this result, we are confident to quickly boost the up- scaled perovskite based PV module efficiency above 15% by using low cost materials and processes. Furthermore, we are working hard to improve the stability of these devices under real life operational conditions. "

The roll-to-roll (R2R) process is developed for both the electron transport and the perovskite layers on the new Solliance dual R2R coating line, as developed by Solliance with its partners VDL Enabling Technologies Group (ETS VDL), Smit Thermal Solutions and Bosch Rexroth. The in-line roll-to-roll coating, drying and annealing processes were executed at a linear speed of 5 m / min on 30-wide commercial PET / ITO foil and under ambient conditions. After applying 0.1cm2, the 12,6cm5 achieves maximum efficiencies of up to 120%, measured under maximum power point tracking conditions during XNUMX minutes. All process steps on this roll-to-roll line have been performed using XNUMX ° C. This shows the high volume production of this new emerging thin film PV technology.


http://www.power-eetimes.com/news/roll- ... efficiency
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Re: Perovskite solar cells - calcium titanate




by PVresistif » 05/02/19, 18:13

perovskite cells this is evolving right now; a factory in Poland is under construction to supply 2020
It should be a small revolution; yield plus 25%, cost -50% and much better production when very little sun (but light)
I look forward to marketing to replace my Unimem solar panel 250W
see also my website: http://osenon.free.fr (chapter 4)
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Re: Perovskite solar cells - calcium titanate




by moinsdewatt » 09/02/20, 20:29

Japan's NEDO and Panasonic Achieve the World's Highest Conversion Efficiency of 16.09% for Largest-area Perovskite Solar Cell Module

IndiaPanasonic Corporation has achieved the world's highest energy conversion efficiency of 16.09% for a perovskite solar module (Aperture area 802 cm2: 30 cm long x 30 cm wide x 2 mm thick) by developing lightweight technology using a glass substrate and a large-area coating method based on inkjet printing. This was carried out as part of the project of the New Energy and Industrial Technology Development Organization (NEDO), which is working on the "Development of Technologies to Reduce Power Generation Costs for High-Performance and High-Reliability Photovoltaic Power Generation" to promote the widespread adoption of solar power generation.

Image

........

Read https://www.socialnews.xyz/2020/02/08/j ... ll-module/
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Re: Perovskite solar cells - calcium titanate




by moinsdewatt » 26/09/20, 21:37

21 cm2 solar cells (perovskite) with an efficiency of 18,1%

Image

A team of researchers from Nanyang Technological University, Singapore (NTU Singapore) created a mini perovskite solar module that achieved the highest energy conversion efficiency of any perovskite based device over 10 cm2 .

......

https://www.enerzine.com/des-cellules-s ... 020-07/amp
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Re: Perovskite solar cells - calcium titanate




by Gaston » 28/09/20, 11:58

So 6 years to go from the laboratory to the prototype ...

And how much more for industrial production?

I note in passing that the "exceptional" laboratory performance of 21% was beaten meanwhile by a silicon cell.
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Re: Perovskite solar cells - calcium titanate




by ENERC » 28/09/20, 13:16

Gaston wrote:So 6 years to go from the laboratory to the prototype ...

And how much more for industrial production?

I note in passing that the "exceptional" laboratory performance of 21% was beaten meanwhile by a silicon cell.

In the meantime we have silicon: (source https://www.energytrend.com/solar-price.html)
- cell price at 18% efficiency: USD 0,085 per Watt
- and $ 0,135 for silicon cells at 21,7% efficiency
We are at 0,24 USD per Watt at the level of a high efficiency panel. In France, it is € 0,30 including tax per Watt for 300 W panels.

The cost of solar panels is about a quarter of the total cost of the installation.

To sum up: the cell weighs between 9 and 13% of the total price of an installation. Gain a few% on the price to replace silicon with lead ... blah
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